If you aren't going to use the compressor as a compressor, shouldn't you just stick with the volume boost you already have?
Also, I would think that different compressors would sound different if used as you are describing, and probably would color the sound a bit since the signal would be going through the circuitry.
I have a Custom Audio Japan V-Comp which is a tube compressor, and the instructions specifically state that you can use it as a volume boost without compressing, but with the purpose of the tube coloring the sound.