Some pedals interact almost as though they were part of the circuitry of the guitar itself. Take for example the stratoblaster (or the active cords that Alembic was selling recently). It doesn't just boost the signal, it actually improves the spectrum of the frequency response. My Zvex Fuzz Factory will self oscillate in several settings, producing squeals and tones reminiscent of analog synth. I can actually change the pitch of these squeals by turning the volume and tone controls on my (passive) guitar. If you place anything that acts as a buffer between this pedal and guitar (such as the aforementioned stratoblaster, or Alembic active electronics), you lose this effect and end up with a flat fizz-less tone (keep this in mind if you are Muse fan, although I have to admit I'm not). You'll experience the same effect with Colorsound One Knob Fuzzes, Tonebenders, Fuzz Faces, and other simple old-school circuits. I'll admit that I don't know the technical specifics of why this happens. I do know that pedals like the Tube King which rely solely on the level of the signal, and which are driven by tubes, do not display this effect. Boss and similar Distortion pedals also don't display this characteristic. It must be related to how the guitar interacts with the bias of the transistors of these circuits, versus the plate voltages of tubes, or circuits which have been designed to emulate tubes. I've been trying for some time to wrap my head around how impedance differs from resistance, but I have yet to understand it. Paging David Fung. . . Dr. Fung?
(Message edited by hydrargyrum on April 21, 2011)